Allyl acetate → 3-(Triphenylsilyl)propan-1-ol

HRID 1252238

반응식

HRID 1252238 반응식
[C:1]1([SiH:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C([O:23][CH2:24][CH:25]=[CH2:26])(=O)C>>[OH:23][CH2:24][CH2:25][CH2:26][Si:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1

참가 물질

3

반응물 2

HCID 11584Allyl acetateHCID 69922Triphenylsilane

생성물 1

HCID 40603353-(Triphenylsilyl)propan-1-ol

실험 절차

The above-mentioned compounds (G-1), (G-2) and (G-3) are prepared by hydrolyzing an adduct (C) of commercially available triphenylsilane (A) and allyl acetate (B) with an alkali to obtain 3-hydroxypropyltriphenylsilane (D) and reacting this compound (D) with acryloyl chloride (E), methacryloyl chloride (E-2) or allyl chloroformate (E-3) in the presence of a dehydrochlorinating agent such as pyridine or triethylamine. ##STR5##

후처리

  1. customThe above-mentioned compounds (G-1), (G-2) and (G-3) are prepared

출처 및 근거

ORD 기록
ord-200b6f90d7334ae683603ecc04a4598c
출처 데이터셋
uspto-grants-1988_05
특허 번호
US04742136

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