Hexachlorocyclotriphosphazene → Trichlorotriphenoxycyclotriphosphazene

HRID 1253343노트

반응식

HRID 1253343 반응식
[Cl:1][P:2]1(Cl)[N:7]=[P:6](Cl)([Cl:8])[N:5]=[P:4]([Cl:11])(Cl)[N:3]=1.[O-:13][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[Na+]>>[Cl:1][P:2]1([O:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[N:7]=[P:6]([Cl:8])([O:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[N:5]=[P:4]([Cl:11])([O:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[N:3]=1

참가 물질

3

반응물 2

HCID 220225Hexachlorocyclotriphosphazene2회HCID 4445035Phenolate Sodium

생성물 1

HCID 23418754Trichlorotriphenoxycyclotriphosphazene

실험 절차

Examples 8 to 12 below illustrate embodiments of the invention in which hexachlorocyclotriphosphazene (compound 1) is reacted first with sodium phenoxide to produce an intermediate (trischlorotrisphenoxycyclotriphosphazene), 19 which is then reacted without separation with sodium 4-nitrophenoxide to afford tris(4-nitrophenoxy)tris(phenoxy)cyclotriphosphazene 20. The nitro groups of 20 are reduced to afford the corresponding tris amino compound 21 which is then used according to Scheme I or Scheme II shown in FIG. 2 and FIG. 3, respectively.

출처 및 근거

ORD 기록
ord-a48308d7f1cd43d988c418c98aaff631
출처 데이터셋
uspto-grants-1988_05
특허 번호
US04748263

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