Hexamethyldisilazane → HCID 178448203, 화합물

HRID 1261551노트

반응식

HRID 1261551 반응식
[CH2:1]([Mg:5]CC)[CH2:2][CH2:3][CH3:4].[CH3:8][Si:9]([CH3:16])([CH3:15])[NH:10][Si:11]([CH3:14])([CH3:13])[CH3:12]>CCCCCCC>[CH3:8][Si:9]([N-:10][Si:11]([CH3:14])([CH3:13])[CH3:12])([CH3:16])[CH3:15].[CH2:1]([Mg+:5])[CH2:2][CH2:3][CH3:4]

참가 물질

4

반응물 2

HCID 13838HexamethyldisilazaneHCID 178448194HCID 178448194, 화합물

생성물 1

HCID 178448203HCID 178448203, 화합물

시약·촉매·용매 1

HCID 8900Heptane용매

실험 절차

A Fischer-Porter test tube size aerosol compatibility vessel is fitted with a tee and valves to maintain a nitrogen atmosphere. A heptane solution of butyl ethyl magnesium (25 mL, 16 mMoles) and hexamethyl disilazane (3.3 mL) are injected by syringe into the tube. Gas is evolved when the two reactants are contacted. After 1 hour and 40 minutes at room temperature, the contents of the tube are transferred to a flask for solvent evaporation without exposing the contents to air. After about four hours at room temperature, with a N2 flow, crystals began to appear in the viscous residue. The following day, the residue appears to be completely solidified. A vacuum is applied for two hours to remove any volatiles.

후처리

  1. customA Fischer-Porter test tube size aerosol compatibility vessel is fitted with a tee and valves
  2. temperatureto maintain a nitrogen atmosphere
  3. custom40 minutes at room temperature, the contents of the tube are transferred to a flask for solvent evaporation
  4. waitAfter about four hours at room temperature
  5. waitA vacuum is applied for two hours
  6. customto remove any volatiles

출처 및 근거

ORD 기록
ord-3c946b0a8b3d45f8a030b81b94a4dfb4
출처 데이터셋
uspto-grants-2013_06
특허 번호
US08470939B2

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