Sodium Cyanide → HCID 11041219, 화합물

HRID 1263049노트

반응식

[C:1]([O:7]C(=O)C(C)(C)C)(=[O:6])[C:2]([CH3:5])([CH3:4])[CH3:3].[C-]#N.[Na+].[CH3:17][Si:18](C#N)([CH3:20])[CH3:19]>>[CH3:17][Si:18]([O:7][C:1](=[O:6])[C:2]([CH3:5])([CH3:4])[CH3:3])([CH3:20])[CH3:19]

참가 물질

반응물 3

HCID 8929Sodium Cyanide

HCID 15234Pivalic anhydride

HCID 82115Trimethylsilyl cyanide

생성물 1

HCID 11041219HCID 11041219, 화합물

실험 절차

93 g (0.5 mol) of pivalic acid anhydride and 1 g of sodium cyanide are initially introduced and 49.5 g (0.5 mol) of trimethylsilyl cyanide are added dropwise. The reaction mixture is worked up by distillation. Yield: 56 g of pivaloyl cyanide (=98.9% of theory). Boiling point: 121°-125° C. In addition, pivalic acid-trimethylsilyl ester is obtained in a corresponding amount (98% of theory).

후처리

distillationThe reaction mixture is worked up by distillation

출처 및 근거

ORD 기록: ord-3f81feee86ec4cf19f0d387980baa039
출처 데이터셋: uspto-grants-1984_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04455264

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