Zirconium chloride (ZrCl4), (T-4)- → HCID 178422508, 화합물

HRID 1264128노트

반응식

HRID 1264128 반응식
[CH3:1][N:2]1[C:10]2[CH:9]=[CH:8][C:7]([CH3:11])=[CH:6][C:5]=2[C:4]2[CH2:12][C:13]3[C:18]([C:3]1=2)=[CH:17][CH:16]=[CH:15][C:14]=3[Li].[Cl-:20].[Cl-].[Cl-].[Cl-].[Zr+4:24]>C(OCC)C>[Cl-:20].[Cl-:20].[CH3:1][N:2]1[C:10]2[CH:9]=[CH:8][C:7]([CH3:11])=[CH:6][C:5]=2[C:4]2[CH2:12][C:13]3[C:18]([C:3]1=2)=[CH:17][CH:16]=[CH:15][C:14]=3[Zr+2:24][C:14]1[CH:15]=[CH:16][CH:17]=[C:18]2[C:13]=1[CH2:12][C:4]1[C:5]3[CH:6]=[C:7]([CH3:11])[CH:8]=[CH:9][C:10]=3[N:2]([CH3:1])[C:3]=12

참가 물질

4

반응물 2

HCID 9856075Zirconium chloride (ZrCl4), (T-4)-HCID 178506659HCID 178506659, 화합물

생성물 1

HCID 178422508HCID 178422508, 화합물

시약·촉매·용매 1

HCID 3283Diethyl Ether용매2회

반응 조건

온도
25 °C

실험 절차

Under the nitrogen protection, 0.24 gram (0.001 mole) of 5,8-dimethyl-5,10-dihydroindeno[1,2-b]indolyllithium is dissolved in 20 mL of diethylether. The solution is slowly added to zirconium tetrachloride (0.12 gram, 0.0005 mole) slurry in 20 mL of diethylether. The mixture is stirred at 25° C. for two hours, filtered, washed with diethylether and dried under vacuum, yielding 0.23 gram of Catalyst III.

후처리

  1. filtrationfiltered
  2. washwashed with diethylether
  3. customdried under vacuum
  4. customyielding 0.23 gram of Catalyst III

출처 및 근거

ORD 기록
ord-b50b1d92c4e34db4a760c880d4fc0fc3
출처 데이터셋
uspto-grants-2003_04
특허 번호
US06541583B2

반응 노트

불러오는 중…