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Water → 2-Hydroxy-3,6-di-n-dodecylaminocarbonylnaphthalene

HRID 1266643
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HRID 1266643 반응식
[OH:1][C:2]1[C:11]([C:12](Cl)=[O:13])=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[C:7]([C:15](Cl)=[O:16])[CH:8]=2)[CH:3]=1.[CH2:18]([NH2:30])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].O>O1CCCC1>[OH:1][C:2]1[C:11]([C:12]([NH:30][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[O:13])=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[C:7]([C:15]([NH:30][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[O:16])[CH:8]=2)[CH:3]=1
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참가 물질

5

반응물 3

HCID 962WaterHCID 13583DodecylamineHCID 18551881HCID 18551881, 화합물

생성물 1

HCID 120674122-Hydroxy-3,6-di-n-dodecylaminocarbonylnaphthalene수율 29%

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매2회

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온도
30 °C

실험 절차

A dispersion of 5.4 g of 2-hydroxy-3,6-dichloro carbonylnaphthalene in 20.0 g of dry tetrahydrofuran was added with 14.8 g of n-dodecylamine solution in 30 g of dry tetrahydrofuran and reacted under reflux for 12 hours. To the reaction mixture, 50 g of water was added and the precipitates were collected by filtration, washed with water and thus obtained crystal was washed with 30 g of methanol under reflux. The obtained mixture was cooled to 30° C. and filtrated, washed with methanol and dried to provide 3.3 g of 2-hydroxy-3,6-di-n-dodecylaminocarbonylnaphthalene (decomposition point: 382.9° C.).

후처리

  1. customreacted
  2. temperatureunder reflux for 12 hours
  3. filtrationthe precipitates were collected by filtration
  4. washwashed with water and thus obtained crystal
  5. washwas washed with 30 g of methanol
  6. temperatureunder reflux
  7. filtrationfiltrated
  8. washwashed with methanol
  9. customdried

출처 및 근거

ORD 기록
ord-b1d37fe7aefe4fe8be0dc75d99fc9528
출처 데이터셋
uspto-grants-2003_04
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US06548703B1

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