Linalool → Citronellol

반응식

C=CC(CCC=C(C)C)(C)O.[OH:12][CH2:13]/[CH:14]=[C:15](/[CH3:22])\[CH2:16][CH2:17][CH:18]=[C:19]([CH3:21])[CH3:20].CC(=CCC/C(=C/CO)/C)C>>[CH3:20][C:19](=[CH:18][CH2:17][CH2:16][CH:15]([CH2:14][CH2:13][OH:12])[CH3:22])[CH3:21]

참가 물질

반응물 3

HCID 6549Linalool

HCID 637566Geraniol2회

HCID 643820Nerol

생성물 1

HCID 8842Citronellol

실험 절차

A portion of the reaction was steam distilled to provide a crude product having a ratio of linalool to nerol plus geraniol to cis- and trans-isogeraniols of 62 to 25 to 13, respectively. The isogeraniols, while not known to be useful in perfumery, can be (like geraniol) hydrogenated to yield citronellol, a valuable perfumery material.

출처 및 근거

ORD 기록: ord-69f66624d4364838ae34db42728b0eff
출처 데이터셋: uspto-grants-1981_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04254291

반응 노트

불러오는 중…