Fluorene → 9-(9H-fluoren-9-ylmethyl)-9H-fluorene

HRID 1275872

반응식

HRID 1275872 반응식
[CH2:1]=[C:2]1[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[C:8]2[C:3]1=[CH:4][CH:5]=[CH:6][CH:7]=2.[CH:15]1[C:27]2[CH2:26][C:25]3[C:20](=[CH:21][CH:22]=[CH:23][CH:24]=3)[C:19]=2[CH:18]=[CH:17][CH:16]=1.CC[O-].[Na+]>CS(C)=O>[CH:13]1[C:14]2[CH:2]([CH2:1][CH:26]3[C:27]4[CH:15]=[CH:16][CH:17]=[CH:18][C:19]=4[C:20]4[C:25]3=[CH:24][CH:23]=[CH:22][CH:21]=4)[C:3]3[C:8](=[CH:7][CH:6]=[CH:5][CH:4]=3)[C:9]=2[CH:10]=[CH:11][CH:12]=1

참가 물질

5

반응물 3

HCID 6853FluoreneHCID 781479-Methylene-9H-fluoreneHCID 2723922Sodium ethoxide

생성물 1

HCID 52459019-(9H-fluoren-9-ylmethyl)-9H-fluorene수율 28.1%

시약·촉매·용매 1

HCID 679Dimethyl Sulfoxide용매

반응 조건

온도
90 °C

실험 절차

A mixture of dibenzofulvene (1 g, 5.68 mmol), fluorene (0.93 g, 5.68 mmol) and EtONa (0.19 g, 2.79 mmol) in DMSO (20 mL) was heated at 90° C. for 16 hours, and was then cooled to room temperature. After carrying out the work-up, as reported in Example 8, 0.55 g of bis(9-fluorenyl)methane were obtained, with a yield of 28%.

후처리

  1. temperaturewas then cooled to room temperature

출처 및 근거

ORD 기록
ord-d3730d209f8c46a38e11b4a9fd7a9f68
출처 데이터셋
uspto-grants-2000_12
특허 번호
US06162937

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