p-Toluenesulfonic acid → Sodium 4-methylbenzenesulfonate

HRID 127727

반응식

HRID 127727 반응식
[N:1]1([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][N:13]2[C:18](=[O:19])[CH2:17][O:16][CH2:15][C:14]2=[O:20])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.CC1C=CC(S(O)(=O)=[O:29])=CC=1.N1(CCCCCCN2C(=O)COCC2=O)CCCCC1.[CH3:52][C:53]1[CH:54]=[CH:55][C:56]([S:59]([OH:62])(=[O:61])=[O:60])=[CH:57][CH:58]=1.[OH-].[Na+:64]>>[N:1]1([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][NH:13][C:14](=[O:20])[CH2:15][O:16][CH2:17][C:18]([O-:29])=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]1.[Na+:64].[S:59]([C:56]1[CH:57]=[CH:58][C:53]([CH3:52])=[CH:54][CH:55]=1)([O-:62])(=[O:61])=[O:60].[Na+:64]

참가 물질

6

반응물 4

HCID 6101p-Toluenesulfonic acidHCID 14798Sodium HydroxideHCID 12796195HCID 12796195, 화합물HCID 12796196HCID 12796196, 화합물

생성물 2

HCID 3720192Sodium 4-methylbenzenesulfonateHCID 23686820HCID 23686820, 화합물

실험 절차

Preparation in situ from 4-(6-piperidinohexyl)-3,5-dioxomorpholine-p-toluenesulfonate. 43 milligrams (0.095 millimole) of 4-(6-piperidinohexyl)-3,5-dioxomorpholine.p-toluenesulfonate (prepared as described in Example IX) was dissolved in 2 milliliters of 0.1 N sodium hydroxide (0.2 millimole) to obtain an aqueous solution of sodium [2-(6-piperidinohexyl)amino-2-oxoethoxy]acetate and sodium tosylate. The solution had the following spectral characteristics:

출처 및 근거

ORD 기록
ord-33a23f1db82a44a883dbaabee6730d1b
출처 데이터셋
uspto-grants-1981_03
특허 번호
US04256891

연결된 노트

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