Benzoyl Peroxide → Ioa iba hea

HRID 1279667

반응식

HRID 1279667 반응식
[C:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]([CH3:13])[CH3:12])(=[O:4])[CH:2]=[CH2:3].[CH3:14][C@@:15]12[CH:23]([C:24]([C:26]([O-:28])=[O:27])=[CH2:25])[CH2:22][C@H:18]([C:19]1([CH3:21])[CH3:20])[CH2:17][CH2:16]2.[C:29]([O:33][CH2:34][CH2:35][OH:36])(=[O:32])[CH:30]=[CH2:31].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.C(Br)(Br)(Br)Br>C(OCC)(=O)C>[C:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]([CH3:13])[CH3:12])(=[O:4])[CH:2]=[CH2:3].[CH3:14][C@@:15]12[CH:23]([C:24]([C:26]([O-:28])=[O:27])=[CH2:25])[CH2:22][C@H:18]([C:19]1([CH3:20])[CH3:21])[CH2:17][CH2:16]2.[C:29]([O:33][CH2:34][CH2:35][OH:36])(=[O:32])[CH:30]=[CH2:31]

참가 물질

7

반응물 5

HCID 7187Benzoyl PeroxideHCID 11205Carbon tetrabromideHCID 131652-Hydroxyethyl acrylateHCID 165746Isooctyl acrylateHCID 92004758Isobomyl acrylate

생성물 1

HCID 131723480Ioa iba hea

시약·촉매·용매 1

HCID 8857Ethyl Acetate용매

반응 조건

온도
60 °C

실험 절차

In a glass polymerization bottle were charged 80 g isooctyl acrylate (IOA), 18 g isobornyl acrylate (IBA), 2 g 2-hydroxyethyl acrylate (HEA), 100 g ethyl acetate, 0.5 g benzoyl peroxide and 0.04 g carbon tetrabromide. The bottle was purged with nitrogen, sealed and tumbled in a water bath maintained at 60° C. for 12 hours to produce an IOA/IBA/HEA terpolymer. The polymer was isolated by precipitation in methanol and dried under vacuum.

후처리

  1. customIn a glass polymerization bottle
  2. customThe bottle was purged with nitrogen
  3. customsealed
  4. customtumbled in a water bath

출처 및 근거

ORD 기록
ord-1525d0c9b5794d729a2e340409a600c2
출처 데이터셋
uspto-grants-2002_09
특허 번호
US06448337B1

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