Potassium Hydroxide → N,N'-bis(4-anilinophenyl)-2,12-dimethyl-4,7,10-trithiatridecanediamide

HRID 1283480

반응식

HRID 1283480 반응식
[SH:1][CH2:2][CH2:3][S:4][CH2:5][CH2:6][SH:7].[NH:8]([C:15]1[CH:20]=[CH:19][C:18]([NH:21][C:22](=[O:26])[C:23]([CH3:25])=[CH2:24])=[CH:17][CH:16]=1)[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[OH-:27].[K+]>C(O)C>[NH:8]([C:15]1[CH:16]=[CH:17][C:18]([NH:21][C:22](=[O:26])[CH:23]([CH3:25])[CH2:24][S:1][CH2:2][CH2:3][S:4][CH2:5][CH2:6][S:7][CH2:24][CH:23]([CH3:25])[C:22]([NH:21][C:18]2[CH:19]=[CH:20][C:15]([NH:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=3)=[CH:16][CH:17]=2)=[O:27])=[CH:19][CH:20]=1)[C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1

참가 물질

5

반응물 3

HCID 14797Potassium HydroxideHCID 77117Bis(2-mercaptoethyl) sulfideHCID 1624682-Propenamide, 2-methyl-N-(4-(phenylamino)phenyl)-

생성물 1

HCID 21518137N,N'-bis(4-anilinophenyl)-2,12-dimethyl-4,7,10-trithiatridecanediamide

시약·촉매·용매 1

HCID 702Ethanol용매2회

반응 조건

온도
50 °C

실험 절차

Sixty-one grams of 2-mercaptoethyl sulfide was added to a solution of 200 grams of N-(4-anilinophenyl) methacrylamide in 2450 milliliters of ethanol. A solution of 5 grams of potassium hydroxide in 50 milliliters of ethanol was then added, and the mixture was heated at 50°C. for 5 hours. Product began to precipitate after about 2 hours. The mixture was then allowed to cool to room temperature and the solid product was filtered off. The product, after drying, weighed 231.5 grams (89 percent of theory) and melted at 131° to 133.5°C.

후처리

  1. customto precipitate after about 2 hours
  2. temperatureto cool to room temperature
  3. filtrationthe solid product was filtered off
  4. customThe product, after drying

출처 및 근거

ORD 기록
ord-2359960700c54f4585be3a0945ea3e63
출처 데이터셋
uspto-grants-1976_08
특허 번호
US03975414

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