Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dimethyl phenylphosphonite → methyl P-phenyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylphosphinate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Dimethyl phenylphosphonite | HCID 76277 | — |
| 반응물 | Benzene, 2-chloro-1-(3,4-dinitrophenoxy)-4-(trifluoromethyl)- | HCID 156238 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 생성물 | methyl P-phenyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylphosphinate | HCID 54521036 | — |
반응 단계
Following the procedure of Example 1, a mixture of 4-(2-chloro-4-trifluoromethylphenoxy)-1,2-dinitrobenzene (2.0 g, 5.52 mmol) and dimethyl phenylphosphonite (1.4 g, 8.28 mmol) in 4 ml of acetonitrile is heated under reflux overnight. The crude product is purified to yield methyl P-phenyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylphosphinate, m/s 471 (M+).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04563310 |
| 출처 데이터셋 | uspto-grants-1986_01 |
| ORD ID | ord-041d5245c1724cad8a4e591d6ebf83dc |
| 출처 메모 | uspto-grants-1986_01 |