Methyl iodide → HCID 20248961, 화합물

HRID 1285334노트

반응식

HRID 1285334 반응식
[CH2:1]([N:8]1[CH2:14][C:12](=[O:13])[NH:11][C:9]1=[S:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[I:15][CH3:16]>CO>[IH:15].[CH2:1]([N:8]1[CH2:14][C:12](=[O:13])[N:11]=[C:9]1[S:10][CH3:16])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

참가 물질

4

반응물 2

HCID 6328Methyl iodideHCID 53685104-Imidazolidinone, 1-(phenylmethyl)-2-thioxo-

생성물 1

HCID 20248961HCID 20248961, 화합물

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

1-Benzyl-2-thiohydantoin (8.07 g), iodomethane (10 ml) and methanol (50 ml) were warmed at 40°-42° C. for 8 hours. The reaction mixture was evaporated under reduced pressure, the residue was washed with diethyl ether and recrystallised from methanol-ethanol to give 1-benzyl-2-methylthio-2-imidazolin-4-one hydroiodide (4.86 g) m.p. 185°-190° C., as an impure light-buff coloured solid which was taken on to the next stage.

후처리

  1. customThe reaction mixture was evaporated under reduced pressure
  2. washthe residue was washed with diethyl ether
  3. customrecrystallised from methanol-ethanol

출처 및 근거

ORD 기록
ord-323d82de3baf487685aa77e1d8b8ca82
출처 데이터셋
uspto-grants-1986_01
특허 번호
US04567176

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