Ethanol, 2-fluoro-2,2-dinitro- → 1-Fluoro-1,1,5-trinitro-3-oxa-5azahexane

반응식

FC(F)(F)C(O[CH2:6][N:7]([N+:9]([O-:11])=[O:10])[CH3:8])=O.[F:14][C:15]([N+:21]([O-:23])=[O:22])([N+:18]([O-:20])=[O:19])[CH2:16][OH:17]>>[F:14][C:15]([N+:21]([O-:23])=[O:22])([N+:18]([O-:20])=[O:19])[CH2:16][O:17][CH2:6][N:7]([N+:9]([O-:11])=[O:10])[CH3:8]

참가 물질

반응물 2

HCID 28189Ethanol, 2-fluoro-2,2-dinitro-

HCID 13352131Acetic acid, trifluoro-, (methylnitroamino)methyl ester

생성물 1

HCID 133521331-Fluoro-1,1,5-trinitro-3-oxa-5azahexane

실험 절차

reacting one mole of 2-nitro-2-azapropyl trifluoroacetate with one mole of 2-fluoro-2,2-dinitroethanol in a polar solvent at a temperature of from 0° C. to 40° C. to form 1-fluoro-1,1,5-trinitro-3-oxa-5azahexane, wherein the reaction is run under vacuum to remove trifluoroacetic acid generated by the reaction; and

후처리

customof from 0° C. to 40° C.

출처 및 근거

ORD 기록: ord-45804309d9454f8fb4d6d054f98606be
출처 데이터셋: uspto-grants-1986_01
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04567296

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