Methyl iodide → HCID 21506179, 화합물

HRID 1287671노트

반응식

HRID 1287671 반응식
[CH3:1]I.[NH2:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[NH:10][C:11](=[S:13])[S-:12].[NH4+]>O>[NH2:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[NH:10][C:11](=[S:12])[S:13][CH3:1]

참가 물질

4

반응물 2

HCID 6328Methyl iodideHCID 2150617649791-42-6

생성물 1

HCID 21506179HCID 21506179, 화합물수율 90%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

Methyl iodide (99.4 g.) is added to a solution of ammonium 2-aminophenyl-dithiocarbamate (141 g.) in water (1050 cc.), whilst keeping the temperature at about 20° C. The mixture is stirred for a further hour after the end of the exothermic reaction. The precipitate obtained is filtered off and is then recrystallized moist from ethanol. Methyl 2-aminophenyl-dithiocarbamate (125 g.), m.p. 114° C., is thus obtained.

후처리

  1. customat about 20° C
  2. customafter the end of the exothermic reaction
  3. customThe precipitate obtained
  4. filtrationis filtered off
  5. customis then recrystallized moist from ethanol

출처 및 근거

ORD 기록
ord-635d87816e674fde85cc40b994212258
출처 데이터셋
uspto-grants-1976_10
특허 번호
US03985782

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