Benzene → Phenylthionophosphonic dichloride

반응식

[P:1]([Cl:5])(Cl)([Cl:3])=[S:2].[CH:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1>>[C:6]1([P:1]([Cl:5])([Cl:3])=[S:2])[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1

참가 물질

반응물 2

HCID 241Benzene

HCID 19883Thiophosphoryl chloride

생성물 1

HCID 19016Phenylthionophosphonic dichloride

반응 조건

온도: 200 °C

실험 절차

In a 100 cc autoclave, 42.35 g (0.25 mole) of thiophosphoryl trichloride, 19.53 g (0.25 mole) of benzene were charged, and the mixture was heated with stirring at 200° C for 4 hours. The reaction mixture was treated in accordance with the process of Example 1. No phenylphosphonothioic dichloride was produced.

후처리

temperaturethe mixture was heated
additionThe reaction mixture was treated in accordance with the process of Example 1

출처 및 근거

ORD 기록: ord-3415756249a948d698066d8c2ad191f4
출처 데이터셋: uspto-grants-1976_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US03988368

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