[1-Methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium iodide → [1-Methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium chloride

HRID 1288519

반응식

HRID 1288519 반응식
[I-].[CH3:2][CH:3]([N+:15]([CH3:25])([CH3:24])[CH2:16][C:17]1[CH:22]=[CH:21][C:20]([Cl:23])=[CH:19][CH:18]=1)/[CH:4]=[CH:5]/[CH:6]1[C:11]([CH3:13])([CH3:12])[CH2:10][CH2:9][CH:8]=[C:7]1[CH3:14]>[Ag]Cl.CO>[Cl-:23].[CH3:2][CH:3]([N+:15]([CH3:25])([CH3:24])[CH2:16][C:17]1[CH:18]=[CH:19][C:20]([Cl:23])=[CH:21][CH:22]=1)/[CH:4]=[CH:5]/[CH:6]1[C:11]([CH3:13])([CH3:12])[CH2:10][CH2:9][CH:8]=[C:7]1[CH3:14]

참가 물질

4

반응물 1

HCID 21502450[1-Methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium iodide

생성물 1

HCID 21502481[1-Methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium chloride수율 111.5%

시약·촉매·용매 2

HCID 24561Silver Chloride촉매HCID 887Methanol용매

실험 절차

A mixture of [1-methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium iodide (2.0 g), silver chloride (1.0 g) and absolute methanol (50 cc) was refluxed for 2 hours, and the reaction mixture was filtered. The solvent of the filtrate was distilled off to give hygroscopic colorless crystals (0.9 g) of [1-methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium chloride.

후처리

  1. temperaturewas refluxed for 2 hours
  2. filtrationthe reaction mixture was filtered
  3. distillationThe solvent of the filtrate was distilled off

출처 및 근거

ORD 기록
ord-ab552f525aed427d99a40a348038bef3
출처 데이터셋
uspto-grants-1976_10
특허 번호
US03988373

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