Oxygen → 1-Carboxy-3-nitro-5-adamantanol

HRID 1296387

반응식

HRID 1296387 반응식
[O:1]=O.[C:3]([C:6]12[CH2:15][CH:10]3[CH2:11][CH:12]([CH2:14][C:8]([N+:16]([O-:18])=[O:17])([CH2:9]3)[CH2:7]1)[CH2:13]2)([OH:5])=[O:4]>C(O)(=O)C>[C:3]([C:6]12[CH2:15][C:10]3([OH:1])[CH2:11][CH:12]([CH2:14][C:8]([N+:16]([O-:18])=[O:17])([CH2:9]3)[CH2:7]1)[CH2:13]2)([OH:5])=[O:4]

참가 물질

4

반응물 2

HCID 977OxygenHCID 392393-Nitrotricyclo(3.3.1.13,7)decane-1-carboxylic acid

생성물 1

HCID 224635701-Carboxy-3-nitro-5-adamantanol수율 80%

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

In an atmosphere of oxygen, the mixture of 10 mmole of 1-carboxy-3-nitroadamantane, 1 mmole of NHPI, 0.05 mmole of V(AA)3 and 25 mL of acetic acid was allowed to react for 4 hours at 85° C. The reaction products were analyzed by gas-mass spectroscopy, and as a result, 1-carboxy-3-nitro-5-adamantanol was formed in a 80% yield.

후처리

  1. customto react for 4 hours at 85° C

출처 및 근거

ORD 기록
ord-42946ffe58bc4a75ba85fef515019366
출처 데이터셋
uspto-grants-2007_07
특허 번호
USRE039744E1

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