2,4,6-Tris((dimethylamino)methyl)phenol → Sodium 2,4,6-tris(dimethylaminomethyl)phenolate

HRID 129901노트

반응식

HRID 129901 반응식
[CH3:1][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:14])[CH3:13])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[OH:19])[CH3:3].[OH-].[Na+:21]>O>[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[Na+:21]

참가 물질

4

반응물 2

HCID 70262,4,6-Tris((dimethylamino)methyl)phenolHCID 14798Sodium Hydroxide

생성물 1

HCID 23711567Sodium 2,4,6-tris(dimethylaminomethyl)phenolate

시약·촉매·용매 1

HCID 962Water용매

실험 절차

53.1 g (0.2 mol) of 2,4,6-tris(dimethylaminomethyl)phenol and 100 ml of H2O are placed in a 500 ml round-bottomed flask having a magnetic stirrer and dropping funnel and, with stirring, 16.0 g (0.2 mol) of a 50% aqueous NaOH solution are added dropwise thereto. The clear, slightly yellow solution is concentrated by evaporation in a rotary evaporator at 70° C., and the residue is dried at 100° C./125 T (16.6×103Pa), yielding 55.1 g of sodium 2,4,6-tris(dimethylaminomethyl)phenolate in the form of a brownish solid of which the elemental analysis is as follows:

후처리

  1. concentrationThe clear, slightly yellow solution is concentrated by evaporation in a rotary evaporator at 70° C.
  2. customthe residue is dried at 100° C./125 T (16.6×103Pa)

출처 및 근거

ORD 기록
ord-3c5191ce46fa44de922b527f60b69675
출처 데이터셋
uspto-grants-1995_11
특허 번호
US05470896

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