반응식
[CH3:1][C:2]1[C:3]2[C:8]([C:9]([CH3:19])=[C:10]3[C:15]=1[CH:14]=[C:13](C(=O)C)[CH:12]=[CH:11]3)=[CH:7][CH:6]=[CH:5][CH:4]=2.Cl([O-])(=O)(=O)=[O:21].[Na+].Cl.[O:27]1[CH2:32]COCC1>>[CH3:1][C:2]1[C:3]2[C:8]([C:9]([CH3:19])=[C:10]3[C:15]=1[CH:14]=[C:13]([C:32]([OH:27])=[O:21])[CH:12]=[CH:11]3)=[CH:7][CH:6]=[CH:5][CH:4]=2참가 물질
5
반응 조건
- 온도
- 85 °C
실험 절차
9,10-Dimethyl-2-acetylanthracene (1.2 g) was dissolved in dioxane (24 mL). An aqueous solution of sodium perchlorate (10 mL; effective chlorine concentration: 10 wt %) was then added, followed by reaction under stirring at 85° C. for 8 hours. The reaction mixture was chilled, and then rendered acidic with dilute hydrochloric acid. The resulting precipitate was collected by filtration, washed with a small amount of water, and then dried in vacuo to afford the target compound (1.16 g).
후처리
- customfollowed by reaction
- temperatureThe reaction mixture was chilled
- filtrationThe resulting precipitate was collected by filtration
- washwashed with a small amount of water
- customdried in vacuo
출처 및 근거
- ORD 기록
- ord-06963fd2f68445c0a7be0ad03d8800fb
- 출처 데이터셋
- uspto-grants-2008_06
- 특허 번호
- US07388110B2
연결된 노트
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