Sodium hydride → HCID 58640416, 화합물
반응식
[CH3:1][C:2]1([CH3:13])[CH2:11][CH2:10][CH2:9][C:8]2[CH:7]=[C:6]([OH:12])[CH:5]=[CH:4][C:3]1=2.[H-].[Na+].Br[CH2:17][C:18]([O:20][C:21]([CH3:24])([CH3:23])[CH3:22])=[O:19]>O1CCCC1>[CH3:1][C:2]1([CH3:13])[CH2:11][CH2:10][CH2:9][C:8]2[CH:7]=[C:6]([O:12][CH2:17][C:18]([O:20][C:21]([CH3:24])([CH3:23])[CH3:22])=[O:19])[CH:5]=[CH:4][C:3]1=2참가 물질
5
실험 절차
A mixture of 5,5-dimethyl-5,6,7,8-tetrahydronaphthalen-2-ol (2.0 g, 11.3 mmol), 60% sodium hydride (542 mg, 13.2 mmol), tert-butyl bromoacetate (3.3 g, 17 mmol) and tetrahydrofuran (THF) (10 ml) was treated in the same procedure described in Example 3(a) to furnish 2.8 g of the title compound as a white solid.
후처리
- additionwas treated in the same procedure
출처 및 근거
- ORD 기록
- ord-e45a36b684a04e32a319486166f23bda
- 출처 데이터셋
- uspto-grants-2007_05
- 특허 번호
- US07214824B2
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