Butanal → 2-Ethylhex-2-Enal

HRID 1356612

반응식

C(=O)CC.C(=O)CCC.[CH2:10]([CH:12]([CH2:15][CH2:16][CH2:17][CH3:18])[CH2:13][OH:14])[CH3:11]>>[CH2:10]([C:12](=[CH:15][CH2:16][CH2:17][CH3:18])[CH:13]=[O:14])[CH3:11]

참가 물질

반응물 3

HCID 261Butanal2회

HCID 527Propanal

HCID 77202-Ethylhexanol

생성물 1

HCID 125822-Ethylhex-2-Enal

실험 절차

The aldol condensation of propanal or butanal is an important step in the production of oxo alcohols such as 2-ethyl hexanol. For example, as described in GB 1462328, butanal is typically condensed using an aqueous caustic catalyst at a temperature of the order of 80 to 140° C. to give 2-ethyl hexenal which is then hydrogenated to 2-ethyl hexanol.

후처리

customcondensed
customat a temperature of the order of 80 to 140° C.

출처 및 근거

ORD 기록: ord-19f0b67242aa4743b6da1498c609c2f7
출처 데이터셋: uspto-grants-2003_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06586636B2

연결된 노트

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