Acrylamide → t-Butylacrylate Acrylamide

HRID 1357849

반응식

HRID 1357849 반응식
[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[C:10]([NH2:14])(=[O:13])[CH:11]=[CH2:12]>C(O)(C)C>[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[C:10]([NH2:14])(=[O:13])[CH:11]=[CH2:12]

참가 물질

4

반응물 2

HCID 6579AcrylamideHCID 15458tert-Butyl acrylate

생성물 1

HCID 86584091t-Butylacrylate Acrylamide

시약·촉매·용매 1

HCID 3776Isopropanol용매

반응 조건

온도
75 °C

실험 절차

To a 500 mL round-bottom, three-neck flask fitted with a thermocouple, reflux condenser, and septum was added 150 mL of isopropanol followed by 16.13 g of a 50% aqueous solution of 2-trimethylammoniumethylacrylate chloride, 8.06 g of t-butylacrylate, and 8.06 g of acrylamide. The solution was purged with nitrogen for 1 hour and 0.5 g AIBN was added. The mixture was purged for ˜15 minutes until all of the AIBN dissolved. The solution was heated to 75° C. under nitrogen for 16 hours.

후처리

  1. customTo a 500 mL round-bottom, three-neck flask fitted with a thermocouple
  2. temperaturereflux condenser
  3. customThe solution was purged with nitrogen for 1 hour
  4. addition0.5 g AIBN was added
  5. customThe mixture was purged for ˜15 minutes until all of the AIBN
  6. dissolutiondissolved

출처 및 근거

ORD 기록
ord-bd62c1d8770a49f6a0a3e87196d92d6c
출처 데이터셋
uspto-grants-2003_07
특허 번호
US06593366B2

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