Toluene → manganese(2+) neodecanoate

HRID 1358895노트

반응식

HRID 1358895 반응식
[O-]S([O-])(=O)=O.[Mn+2:6].O.C1(C)C=CC=CC=1.[C:15]([O-:26])(=[O:25])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][C:21]([CH3:24])([CH3:23])[CH3:22].[Na+]>O>[C:15]([O-:26])(=[O:25])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][C:21]([CH3:22])([CH3:23])[CH3:24].[Mn+2:6].[C:15]([O-:26])(=[O:25])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][C:21]([CH3:22])([CH3:23])[CH3:24]

참가 물질

5

반응물 3

HCID 1140TolueneHCID 177577Manganese sulfate monohydrateHCID 236891301135294-90-4

생성물 1

HCID 22315822manganese(2+) neodecanoate

시약·촉매·용매 1

HCID 962Water용매

실험 절차

Manganese neodecanoate was prepared by the following procedure: 8.45 g (0.05 moles) of MnSO4.H2O was dissolved in 50 g of water. 50 ml of toluene was added, and with vigorous stirring 77.6 g of a 25% solution of sodium neodecanoate (0.1 moles) was added in about 10 minutes. Rapid stirring was continued for 10 minutes after the addition was complete, stirring was discontinued, and the mixture was allowed to stand for 10 minutes to separate to a dark red organic phase and a clear colorless water phase. The organic phase weighed 87 g and contained 25% manganese neodecanoate, which after removing the solvent by evaporation was a dark red viscous liquid with viscosity>200,000 cps.

후처리

  1. additionwas added in about 10 minutes
  2. additionafter the addition
  3. stirringstirring
  4. waitto stand for 10 minutes
  5. customto separate to a dark red organic phase
  6. customafter removing the solvent
  7. customby evaporation

출처 및 근거

ORD 기록
ord-6fc9b236a9d04917b0f98a1f73f21de8
출처 데이터셋
uspto-grants-2003_07
특허 번호
US06599472B1

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