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망간 설페이트 모노하이드레이트

Manganese sulfate monohydrate

HCID 177577
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기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
10034-96-5
표준 SMILES
O.O=S(=O)([O-])[O-].[Mn+2]
InChIKey
ISPYRSDWRDQNSW-UHFFFAOYSA-L
분자식
H2MnO5S
평균 분자량
169.02 g/mol
단동위원소 질량
168.900337

이름 및 식별자

우선 이름
Manganese sulfate monohydrate
IUPAC
manganese(2+);sulfate;hydrate
현지명
망간 설페이트 모노하이드레이트
영어명
Manganese sulfate monohydrate
분자식
H2MnO5S
분자량
169.02

이름 및 동의어

10034-96-5Manganese(II) sulfate monohydrateMANGANESE SULFATE MONOHYDRATEMnSO4.H2OManganous sulfate monohydrateManganese(2+) sulfate monohydrateDTXSID4020795Manganese sulfate (USP)CHEBI:86364Sulfuric acid, manganese(2+) salt (1:1) monohydrateRefChem:889804DTXCID00795
이름 더 보기
망간설페이트모노하이드레이트아망가니즈황산염모노수화물아망가니즈산황산염모노수화물황산망간아망가니즈황산염모노수화물망가니즈 황산 모노수화물망간(II)황산염일수화물MANGANESE SULFATE, MONOHYDRATEMANGANESE SULFATE, MONOHYDRATEMANGANESE(II) SULFATE-1-HYDRATEKH2PO30MANGANOUS SULFATEManfanous sulfateManganesu SulphateWinkler's solution #1
600-072-9Manganese sulfate (MnSO4) monohydrateManganese, monosulfate, monohydrate15244-36-7Manganese sulfate hydrateManganese(II) sulfate hydrateManganese sulfate xhydrateManganese sulphate monohydrate

데이터베이스 식별자

CAS
10034-96-5、15244-36-7
PubChem CID
177577
DTXSID
DTXSID4020795
ChEBI
CHEBI:86364
UNII
W00LYS4T26
EC Number
600-072-9、629-492-0、918-733-8
Nikkaji
J605.509E

물성

구조 계산 물성보충 중

극성 표면적
89.6 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
5
회전 가능 결합 수
0
무거운 원자 수
7
형식 전하
0
복잡도
62

실험 및 물리화학적 성질

Density · 3건

2.95 (NTP, 1992) - Denser than water; will sink

Relative density (water = 1): 2.95

3.25 @25 °C

Solubility · 2건

50 to 100 mg/mL at 70 °F (NTP, 1992)

Solubility in water, g/100ml: 76.2 (freely soluble)

Melting Point · 3건

greater than 752 °F (NTP, 1992)

400-450 °C

700 °C

Physical Description · 4건

Manganese(ii) sulfate monohydrate appears as odorless pale red slightly efflorescent crystals or light pink powder. pH (5% solution) 3.7. (NTP, 1992)

Dry Powder; Other Solid; Dry Powder; Liquid; Liquid

Light red solid; Slightly efflorescent; [Merck Index] Pink hygroscopic solid; [ICSC] Light red hygroscopic powder; [Aldrich MSDS]

PINK HYGROSCOPIC CRYSTALS.

물리화학적 성질

녹는점
700 °C · 700 °C
끓는 점
850 °C · 850 °C
밀도
2.95 · 2.95
굴절률
1.508 · 1.508-1.522
저장 조건
15 °C · Store at +15°C to +25°C.
용해도
21 °C에서 · 21°C에서 5~10g/100mL

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 0.1% (2 of 1512) of reports.

Warning

H373 (99.7%): May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure];H411 (99.7%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P260, P273, P319, P391, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 1512 reports by companies from 23 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 2 of 1512 reports by companies.;There are 22 notifications provided by 1510 of 1512 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 4건

Chemical: Sulfuric acid, manganese(2+) salt (1:1), monohydrate

Regulation (EC) No 1831/2003 (amended)

Sulfuric acid, manganese(2+) salt (1:1) monohydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, manganese(2+) salt (1:1) monohydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Manganese (II) sulphate, monohydrate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Soluble manganese compounds: Human health tier II assessment
DOT LabelClass 9

화학 및 산업

용도 및 제조

Uses · 3건

Used in dyes, boiling oils for varnishes, fertilizers (vines and tobacco), animal feeds (essential trace element), red glazes on porcelain, and medicines (prevention of perosis in poultry); [Merck Index] Used in paints, varnishes, textile dyes, fungicides, medications, ceramics, foods (nutrient and dietary supplement), ore flotation, and synthetic manganese dioxide; Also used as a catalyst (viscose process); [NTP]

Painting (Pigments, Binders, and Biocides) [Category: Paint];Farming (Pesticides) [Category: Industry];Textiles (Printing, Dyeing, or Finishing) [Category: Industry];Metal Extraction and Refining [Category: Industry];Farming (Feed Additives) [Category: Industry]

Ceramics making [Category: Hobbies];Enameling [Category: Hobbies]

U.S. Production2023: 250,000 - <400,000 lb;2022: 250,000 - <550,000 lb;2021: 1,000,000 - <5,000,000 lb;2020: 1,000,000 - <5,000,000 lb
Consumer UsesSoil amendments (fertilizers);Not Known or Reasonably Ascertainable
Industry UsesNot Known or Reasonably Ascertainable;Soil amendments (fertilizers)
General Manufacturing InformationPesticide, Fertilizer, and Other Agricultural Chemical Manufacturing;Agriculture, Forestry, Fishing and Hunting;Not Known or Reasonably Ascertainable
응용 분야 · 2건

용도Manganese sulfate monohydrate is used to produce manganese by an electrolytic process. The compound is used for dyeing textiles; for producing red glazes on porcelain; in varnish driers; in fertilizers; and in animal feeds to provide manganese as an essential trace element.

일반 설명Odorless pale red slightly efflorescent crystals or light pink powder. pH (5% solution) 3.7.

제조 방법 · 1건

관련 반응

15건
반응 기록 만들기
HRID 10125 반응식
HRID 10125촉매로uspto-grants-2006_08
HRID 232510 반응식
HRID 232510촉매로uspto-grants-1997_01
HRID 275250 반응식
HRID 275250촉매로uspto-grants-1995_02
HRID 523847 반응식
HRID 523847생성물로uspto-grants-2016_05
HRID 637618 반응식
HRID 637618촉매로uspto-grants-1985_12
HRID 742183 반응식
HRID 742183촉매로uspto-grants-1996_09
HRID 1075440 반응식
HRID 1075440반응물로uspto-grants-1999_05
HRID 1243240 반응식
HRID 1243240촉매로uspto-grants-2006_10
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화합물 노트

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이 페이지에서기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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물리적 상태
고체
색상
분홍색
냄새
Odorless
수소이온지수(pH)
3 · 3.0-3.5 (50g/l, H2O, 20℃)
수용성
21 · 21&C에서 5~10g/100mL
Merck
14 · 14,5739
InChI
1S/Mn.H2O4S.H2O/c;1-5(2,3)4;/h;(H2,1,2,3,4);1H2/q+2;;/p-2
InChIKey
ISPYRSDWRDQNSW-UHFFFAOYSA-L
SMILES
O.[Mn++].[O-]S([O-])(=O)=O
LogP
-1.031 · -1.031 (est)
EPA
Manganese(II) sulfate monohydrate (10034-96-5)

화학적 성질

Pale pink crystalline powder, slightly hygroscopic

Fire Hazards · 2건

Flash point data for this chemical are not available; however, it is probably combustible. (NTP, 1992)

Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

Health Hazards · 1건

SYMPTOMS: Symptoms of exposure to this compound include mild irritation of the eyes and mucous membranes of the respiratory tract. Symptoms of exposure to this type of compound include apathy, anorexia, headache, recurring leg cramps, loss of balance, clumsiness, pneumonia and associated pulmonary problems. Other symptoms include central nervous system damage, pulmonary system damage, upper respiratory infections, languor, sleepiness, weakness in the legs, a stolid, mask-like face, muscular twitchings, varying from a fine tremor of the hands to coarse, rhythmical movements of the arms, legs and trunk; slight increase in tendon reflexes, ankle and patellar clonus, typical Parkinsonian slapping gait and minute handwriting (affected by micrographia). It can cause spastic gait, insomnia, dystonia, fatiguability, asthenia and an inability to concentrate. It can also cause impaired mentation, ataxia, difficulty in walking and decreased movement of the eyelids and eyes. Other symptoms include lethargy, edema, extrapyramidal effects, sleep disturbances, dermatitis, irritability, liver enlargement, increased muscle tone, muscular cramps, mental deterioration, excessive salivation and perspiration, sexual disturbances, blood changes and, very rarely, hypothyroidism. Exposure can cause spasms, arthralgias and speech disturbances such as slurred speech, slow and monotonous voice tone, inability to speak above a whisper, difficult articulation and incoherence, and even complete muteness. Psychosis may occur with unaccountable laughter, euphoria, impulsive acts, absentmindedness, mental confusion, aggressiveness and hallucinations. Propulsion, retropropulsion and lateropropulsion are affected with no movement for protection when falling. Absolute detachment may occur, broken by sporadic or spasmodic laughter. Inhalation may cause acute bronchitis, nasopharyngitis and itching. Numbness of the extremities and impairment of libido may occur. Other effects include weakness, delusions;ACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits toxic fumes of sulfur oxides. (NTP, 1992)

Hazards Summary · 1건

No evidence of carcinogenicity in rats and equivocal evidence in mice in 2-year feeding studies; [NTP] Intermittent inhalation studies of rats produced changes in testicular weight (0.5 mg/m3 for 45 days) and degenerative changes to brain (0.01 mg/m3 for 13 weeks); [RTECS] May cause irritation; Targets lungs and nerves; [Aldrich MSDS] See Manganese and linked occupational diseases.

Reactive GroupSalts, Acidic
UN ClassificationUN Hazard Class: 9; UN Pack Group: III
Reactivity ProfileMANGANESE(II) SULFATE MONOHYDRATE is incompatible with aluminum and magnesium. (NTP, 1992)
Chemical DangersDecomposes on heating. This produces sulfur oxides and manganese oxides. This generates toxic hazard.
Air and Water ReactionsWater soluble. Hygroscopic.
Hazard Classes and Categories · 5건

STOT RE 2 (99.7%);Aquatic Chronic 2 (99.7%)

STOT RE 2 (100%);Aquatic Chronic 2 (100%)

Acute toxicity - category 4;Eye damage - category 1;Specific target organ toxicity (repeated exposure) - category 1

Germ cell mutagenicity - Category 2

Acute toxicity (Oral) - Category 4;Serious eye damage/eye irritation - Category 1;Germ cell mutagenicity - Category 2;Reproductive toxicity - Category 1B;Specific target organ toxicity - Repeated exposure - Category 1 (central nervous system, respiratory organs)

안전 및 보호

Fire Fighting · 2건

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)

In case of fire in the surroundings, use appropriate extinguishing media.

First Aid Measures · 3건

Fresh air, rest.

Rinse with plenty of water for several minutes (remove contact lenses if easily possible).

Rinse mouth. Seek medical attention if you feel unwell.

First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.;SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.;INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.;INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Safe StorageDry. Well closed. Store in an area without drain or sewer access.
Exposure Control and Personal Protection0.2 [mg/m3], as Mn (inhalable fraction), 0.02 mg/m3, as Mn (respirable fraction)[German Research Foundation (DFG)]
Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.;STORAGE PRECAUTIONS: You should store this chemical under ambient temperatures, and protect it from moisture. If possible, it would be prudent to store this compound under inert atmosphere. (NTP, 1992)

Spillage Disposal · 1건

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water. Store and dispose of according to local regulations.

Isolation and Evacuation · 1건

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:;IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.;SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.;FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)

Eye PreventionWear safety spectacles or eye protection in combination with breathing protection if powder.
Inhalation RiskEvaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed, especially if powdered.
Skin PreventionProtective gloves.
Exposure PreventionPREVENT DISPERSION OF DUST!

독성 정보

Adverse EffectsNeurotoxin - Parkinsonism
Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol and by ingestion.
Signs and Symptoms · 3건

Cough. Sore throat. Shortness of breath.

Redness. Pain.

Sore throat.

ICSC Environmental DataThe substance is toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment.
Carcinogen Classification · 6건

Manganese Sulfate Monohydrate

TR-428: Toxicology and Carcinogenesis Studies of Manganese (II) Sulfate Monohydrate (CASRN 10034-96-5) in F344/N Rats and B6C3F1 Mice (Feed Studies) (1993 )

06/23/92

No Evidence

No Evidence

Equivocal Evidence

규제 정보

Regulatory Information · 4건

Chemical: Sulfuric acid, manganese(2+) salt (1:1), monohydrate

Regulation (EC) No 1831/2003 (amended)

Sulfuric acid, manganese(2+) salt (1:1) monohydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, manganese(2+) salt (1:1) monohydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Manganese (II) sulphate, monohydrate: Does not have an individual approval but may be used under an appropriate group standard

안전 데이터

wgk
1
tsca
Yes
rtecs
OP0893500
ridadr
UN 3077 9/PG 3
독성
LD50 orally in Rabbit: 2150 mg/kg
HS 번호
2833299090
risk_code
48/20/22-51/53
hazard_code
Xn,N
safety_code
22-61
포장분류
III
위험 등급
9
F 고인화성물질
3
Hazard Classifications
Aquatic Chronic 2Eye Dam. 1STOT RE 2 Inhalation
스토리지 클래스
13 - Non Combustible Solids

Manganese(II) sulfate is prepared by prolonged heating of any manganese salt with concentrated sulfuric acid. The compound is produced commercially from pyrolusite (MnO2) or rhodochrosite (MnCO3). Either mineral is dissolved in sulfuric acid and the solution evaporated: MnO2 + H2SO4 → MnSO4 + H2O + ½ O2 Alternatively, manganese dioxide is heated strongly with dehydrated iron(II) sulfate: 2MnO2 + 2FeSO4 → 2MnSO4 + Fe2O3 + ½ O2 Manganese(II) sulfate, prepared by methods involving evaporation of manganese salt with sulfuric acid, is the tetrahydrate, MnSO4•4H2O. The tetrahydrate on gentle heating produces monohydrate, MnSO4•H2O. Also, manganese(II) sulfate is a by-product in the manufacture of hydroquinone. The process involves reaction of aniline with manganese dioxide in sulfuric acid, followed by the removal of quinone by steam distillation under vacuum. 2C6H5NH2 (aniline) + 5H2SO4 + 4MnO2 → 2C6H4O2 + 4MnSO4 + 2C6H4O2 + 4MnSO4(quinone) The unreacted acid is neutralized by lime, treated with water, and the solution filtered to separate any excess MnO2 and insoluble residues. Evaporation of the filtrate yields a crude product containing about 80% MnSO4 and 15% (NH4)2SO4. Manganese(II) sulfate also may be produced by the action of sulfur dioxide with manganese dioxide: MnO2 + SO2 → MnSO4

상·하류 제품 정보

상류 원료

Manganese dioxide powderIron filingsdilute sulphuric acid이산화 망간삼산화 망간산화 망간망간분하이드로퀴논황철광황화 바륨황산제일철7수화물황산

하류 제품

만코제브3-메톡시이소니코틴알데하이드망간 2-에틸헥산산염Electrolytic manganese bioxide망간 인산염Rare earth drier1-메틸-1H-이미다졸-5-카르복스알데히드Foliar-fertilizerManganese naphthenateMixed and compound fertilizer탄산망간Mancozeb WP암모니아(가스)