Hydrochloric Acid → HCID 22607995, 화합물
반응식
[C:1]1([S:7][C:8]2[CH:9]=[C:10]([CH:14]3OCC[O:15]3)[CH:11]=[CH:12][CH:13]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Cl>C(#N)C>[C:1]1([S:7][C:8]2[CH:9]=[C:10]([CH:11]=[CH:12][CH:13]=2)[CH:14]=[O:15])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1참가 물질
4
실험 절차
Combine 2-(3-phenylsulfanylphenyl)-[1,3]-dioxolane (0.3 g, 1.1 mmol) and acetonitrile (8.0 ml) add a solution of hydrochloric acid (1N, 2.0 ml). After 18 hours, concentrate in vacuum to remove most of the acetonitrile, dilute with water and extract with ether. Combine the organic extracts and wash once with saturated sodium bicarbonate, then with brine. Dry (Na2SO4) the organics, filter, and concentrated to give the title compound.
후처리
- concentrationconcentrate in vacuum
- customto remove most of the acetonitrile
- additiondilute with water
- extractionextract with ether
- washwash once with saturated sodium bicarbonate
- dry with materialDry (Na2SO4) the organics,
- filtrationfilter
- concentrationconcentrated
출처 및 근거
- ORD 기록
- ord-3a81f9daeeb04bad8c589b50f3f5a9b8
- 출처 데이터셋
- uspto-grants-2007_01
- 특허 번호
- US07157488B2
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