HCID 12094927, 화합물 → HCID 12094928, 화합물

HRID 1373989노트

반응식

HRID 1373989 반응식
[C:1]1([C:6]2[CH:7]=[C:8]([CH2:12][OH:13])[CH:9]=[CH:10][CH:11]=2)[CH2:5][CH2:4][CH2:3][CH:2]=1>O=[Mn]=O.C(Cl)(Cl)Cl>[C:1]1([C:6]2[CH:7]=[C:8]([CH:9]=[CH:10][CH:11]=2)[CH:12]=[O:13])[CH2:5][CH2:4][CH2:3][CH:2]=1

참가 물질

4

반응물 1

HCID 12094927HCID 12094927, 화합물

생성물 1

HCID 12094928HCID 12094928, 화합물수율 76.2%

시약·촉매·용매 2

HCID 14801Manganese dioxide촉매HCID 6212Chloroform용매

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온도
60 °C

실험 절차

1.35 g (8 mmol) of (3-cyclopenten-1-ylphenyl)methanol (5a) and 80 ml of chloroform are introduced into a round-bottomed flask. 6.8 g of MnO2 are then added and the suspension is heated at 60° C. for 2 hours. The mixture is filtered in the hot state, the precipitate washed with chloroform and then the filtrate concentrated under reduced pressure. The title product (1.05 g) is obtained in the form of a yellow oil which is used in the next step without further purification.

후처리

  1. filtrationThe mixture is filtered in the hot state
  2. washthe precipitate washed with chloroform
  3. concentrationthe filtrate concentrated under reduced pressure

출처 및 근거

ORD 기록
ord-91e66b52a2694e669d576b4da976f71f
출처 데이터셋
uspto-grants-2007_01
특허 번호
US07163957B2

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