5-(2-Butyl-1,3-dithiolan-2-yl)benzene-1,3-diol → 5-(1-Cyclopentyl-1-methyl-ethyl)-benzene-1,3-diol

HRID 1376249

반응식

HRID 1376249 반응식
[CH:1]1([C:6]([C:9]2[CH:14]=[C:13]([O:15]C)[CH:12]=[C:11]([O:17]C)[CH:10]=2)([CH3:8])[CH3:7])[CH2:5][CH2:4][CH2:3][CH2:2]1.C(C1(C2C=C(O)C=C(O)C=2)SCCS1)CCC>CCCCCC.C(OCC)C>[CH:1]1([C:6]([C:9]2[CH:14]=[C:13]([OH:15])[CH:12]=[C:11]([OH:17])[CH:10]=2)([CH3:8])[CH3:7])[CH2:5][CH2:4][CH2:3][CH2:2]1

참가 물질

4

반응물 2

HCID 3176955-(2-Butyl-1,3-dithiolan-2-yl)benzene-1,3-diolHCID 668861281-(1-Cyclopentyl-1-methyl-ethyl)-3,5-dimethoxy-benzene

생성물 1

HCID 450936235-(1-Cyclopentyl-1-methyl-ethyl)-benzene-1,3-diol

시약·촉매·용매 1

HCID 21584099Diethylether hexane용매

실험 절차

Compound 20 was prepared from Compound 13 using the same procedure as described above for Compound 16. Yield 1.29 g (72.9%) as a viscous oil. Rf=0.28 (hexane:diethyl ether 6:4); 1H NMR δ 6.44 (d, J=2.1 Hz, 2H), 6.20 (t, J=2.1 Hz, 1H), 5.70 (br s, 2H), 2.02–1.98 (m, 1H), 1.57–1.35 (m, 6H), 1.18 (s, 6H); 13C NMR δ 156.22, 154.66, 105.10, 99.83, 53.24, 50.33, 36.21, 24.99, 24.75; MS: (ESI, Neg.) m/z 219 ([M−H]−).

출처 및 근거

ORD 기록
ord-89f2b02163ec4d999d1c7fed66ebf277
출처 데이터셋
uspto-grants-2007_01
특허 번호
US07169942B2

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