HCID 13187346, 화합물 → HCID 13187370, 화합물

HRID 1379976노트

반응식

HRID 1379976 반응식
[Cl:1][CH2:2][C:3]([C:5]1[CH:10]=[CH:9][C:8]([N+:11]([O-:13])=[O:12])=[CH:7][CH:6]=1)=[CH2:4]>C1(C)C=CC=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.[Cl-].[Rh]>[Cl:1][CH2:2][CH:3]([C:5]1[CH:10]=[CH:9][C:8]([N+:11]([O-:13])=[O:12])=[CH:7][CH:6]=1)[CH3:4]

참가 물질

4

반응물 1

HCID 13187346HCID 13187346, 화합물

생성물 1

HCID 13187370HCID 13187370, 화합물

시약·촉매·용매 2

HCID 84599Chlorotris(triphenylphosphine)rhodium(I)촉매HCID 1140Toluene용매

실험 절차

A solution of 51.3 g (0.26 Mol) of 4(1-chloromethyl-ethenyl)-nitrobenzene and 10 g of tris(triphenylphosphine)-rhodium (I) chloride in 1000 ml of dry toluene is hydrogenated at ambient temperature and atmospheric pressure.

후처리

  1. customis hydrogenated at ambient temperature

출처 및 근거

ORD 기록
ord-f7ec7062683c449c8b70df5cf53bfac9
출처 데이터셋
uspto-grants-1986_04
특허 번호
US04579585

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