Benzoic Acid → HCID 23325079, 화합물

HRID 1381032

반응식

HRID 1381032 반응식
[CH:1]([Si:3](Cl)(Cl)Cl)=[CH2:2].[C:7]([OH:15])(=[O:14])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1.ClCl>CCCCCC>[CH:1]([Si:3]([O:15][C:7](=[O:14])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)([O:14][C:7](=[O:15])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[O:14][C:7](=[O:15])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)=[CH2:2]

참가 물질

5

반응물 3

HCID 243Benzoic AcidHCID 6413VinyltrichlorosilaneHCID 24526Chlorine

생성물 1

HCID 23325079HCID 23325079, 화합물

시약·촉매·용매 1

HCID 8058Hexane용매

실험 절차

A six-liter three-necked flask is placed in a mushroom heating hood, and equipped with a stirrer, a reflux condenser and a dropping funnel whose nozzle bore amounts to 1 cm. 808 g (5 moles) of vinyltrichlorosilane and 1000 ml of hexane are introduced into the flask. The outlet from the reflux condenser is shielded with nitrogen. After the liquid has been heated until an intensive refluxing is taking place at the condenser, 1855 g (15.2 mol) of benzoic acid is added in 30-gram portions. The addition is completed in about 20 hours. The reaction is allowed to run, with refluxing and vigorous stirring, until the analytically determined contents of hydrolyzable chlorine amount to less than 100 parts per million.

후처리

  1. temperatureheating hood
  2. customequipped with a stirrer, a reflux condenser and a dropping funnel whose nozzle
  3. temperatureAfter the liquid has been heated until
  4. temperaturean intensive refluxing
  5. additionis added in 30-gram portions
  6. additionThe addition
  7. temperaturewith refluxing

출처 및 근거

ORD 기록
ord-f45aa8f080f9461a9d27ca2022d71892
출처 데이터셋
uspto-grants-1986_04
특허 번호
US04584394

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