Phosphoric Acid → 6-Deoxy-6-(formylamino)-L-sorbose

HRID 1382490노트

반응식

HRID 1382490 반응식
P(=O)(O)(O)O.[CH:6]([NH:8][CH:9]([C@@H:11]([C@H:13]([C@@H:15]([C@@H:17]([CH2:19][OH:20])[OH:18])[OH:16])[OH:14])[OH:12])O)=[O:7]>O>[CH:6]([NH:8][CH2:9][C@H:11]([OH:12])[C@@H:13]([OH:14])[C@H:15]([OH:16])[C:17](=[O:18])[CH2:19][OH:20])=[O:7]

참가 물질

4

반응물 2

HCID 1004Phosphoric AcidHCID 131715863HCID 131715863, 화합물2회

생성물 1

HCID 228415056-Deoxy-6-(formylamino)-L-sorbose

시약·촉매·용매 1

HCID 962Water용매

실험 절차

To a suspension of 40 g of Gluconobacter oxidans spp. suboxidans (DSM 50049) in 1 l of tap water, brought to pH 4.5 with phosphoric acid, are added at 32° C. and 700 rpm with venting of 3 l of air/hour 200 g of N-formylaminosorbitol, followed 4 hours later by a further 200 g of N-formylaminosorbitol. After 22 hours the reaction has ended, the cells are centrifuged off and discarded. The product is isolated as an oil by concentrating in vacuo.

후처리

  1. additionare added at 32° C.
  2. customThe product is isolated as an oil
  3. concentrationby concentrating in vacuo

출처 및 근거

ORD 기록
ord-492164ec61bd40329d8a7b27a129fa0f
출처 데이터셋
uspto-grants-1989_02
특허 번호
US04806650

반응 노트

불러오는 중…