Potassium Hydroxide → HCID 13281343, 화합물
반응식
[Cl:1][C:2]1[C:13]2[CH2:12][CH2:11][CH2:10][C:9](=O)[C:8]3[CH:15]=[CH:16][CH:17]=[CH:18][C:7]=3[C:6]=2[CH:5]=[CH:4][CH:3]=1.O.NN.[OH-].[K+]>C(O)CO>[Cl:1][C:2]1[C:13]2[CH2:12][CH2:11][CH2:10][CH2:9][C:8]3[CH:15]=[CH:16][CH:17]=[CH:18][C:7]=3[C:6]=2[CH:5]=[CH:4][CH:3]=1참가 물질
5
실험 절차
The reaction of 9-chloro-5,6,7,8-tetrahydrodibenzo[a,c]-cycloocten-5-one (3.0 g, 0.015 mole), 85% hydrazine hydrate (4.5 g, 0.076 mole), potassium hydroxide (3.0 g, 0.046 mole) and ethylene glycol (39 ml) produced an oil. The oil was purified by column chromatography on silica gel, eluted with toluene to yield 4-chloro-5,6,7,8-tetrahydrodibenzo[a,c]cyclooctene as an oil (3.3 grams).
후처리
- customproduced an oil
- customThe oil was purified by column chromatography on silica gel
- washeluted with toluene
출처 및 근거
- ORD 기록
- ord-c62c125314254b93aa856cfdefdc59df
- 출처 데이터셋
- uspto-grants-1984_02
- 특허 번호
- US04433182
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