Allyl bromide → N,N-Dimethyl-N-(prop-2-en-1-yl)octadecan-1-aminium chloride

HRID 1388870

반응식

HRID 1388870 반응식
[CH3:1][N:2]([CH3:21])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[CH2:22]([Cl:25])[CH:23]=[CH2:24].C(Br)C=C.C(=O)(O)[O-].[Na+]>C(O)(C)C>[Cl-:25].[CH2:22]([N+:2]([CH3:1])([CH3:21])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])[CH:23]=[CH2:24]

참가 물질

6

반응물 4

HCID 7841Allyl bromideHCID 7850Allyl chlorideHCID 15365DimethyloctadecylamineHCID 516892Sodium Bicarbonate

생성물 1

HCID 20468836N,N-Dimethyl-N-(prop-2-en-1-yl)octadecan-1-aminium chloride

시약·촉매·용매 1

HCID 3776Isopropanol용매

실험 절차

A 2-liter reaction vessel equipped with a mechanical stirrer and a reflux condenser was charged with 660.0 gm. dimethyl octadecyl amine, 199.0 gm. (2.19 mol) allyl chloride, 13.3 (0.11 mol) gm. allyl bromide, 20 gm. sodium bicarbonate, and 350 ml. isopropyl alcohol. This mixture was heated under reflux overnight. Analyses of a filtered aliquot indicated the reaction was complete. The mixture was filtered and upon analysis had an Effective gram MW of 496.74.

후처리

  1. customA 2-liter reaction vessel
  2. customequipped with a mechanical stirrer and a reflux condenser
  3. additionwas charged with 660.0 gm
  4. temperatureThis mixture was heated
  5. temperatureunder reflux overnight
  6. filtrationThe mixture was filtered and upon analysis

출처 및 근거

ORD 기록
ord-31c201d1fc7b4a01b6dd2e904ca8cfbe
출처 데이터셋
uspto-grants-1984_02
특허 번호
US04434076

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