Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium borohydride → 1,5-Di-(3,3-dimethylnorborn-2-yl)-3-pentanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium borohydride | HCID 4311764 | — |
| 반응물 | 1,5-Di-(3,3-dimethylnorborn-2-yl)-3-pentanone | HCID 21332846 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 1,5-Di-(3,3-dimethylnorborn-2-yl)-3-pentanol | HCID 21332842 | — |
반응 단계
The ketone, 1,5-di-(3,3-dimethylnorborn-2-yl)-3-pentanone (2 grams) was dissolved in 100 ml. of ethanol and stirred with 2 grams of sodium borohydride overnight. The solvent was removed in vacuo and the residue partitioned between ethyl ether and water. The organic layer was dried over sodium sulfate. After filtration, and removal of solvent a colorless oil was obtained that crystallized on standing, m.p. 55° C.-56° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04139559 |
| 출처 데이터셋 | uspto-grants-1979_02 |
| ORD ID | ord-8e660559ec5a4d1a89cdbf6e555f403d |
| 출처 메모 | uspto-grants-1979_02 |