Potassium Permanganate → HCID 12806656, 화합물

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[C:1]([C:6]1[C:17]([Cl:18])=[CH:16][C:9]2[N:10]([CH3:15])[C:11]([CH2:13][OH:14])=[N:12][C:8]=2[CH:7]=1)(=[O:5])[CH2:2][CH2:3][CH3:4].[Mn]([O-])(=O)(=O)=[O:20].[K+]>>[C:1]([C:6]1[C:17]([Cl:18])=[CH:16][C:9]2[N:10]([CH3:15])[C:11]([C:13]([OH:20])=[O:14])=[N:12][C:8]=2[CH:7]=1)(=[O:5])[CH2:2][CH2:3][CH3:4]

참가 물질

반응물 2

HCID 516875Potassium Permanganate

HCID 130606791-(6-Chloro-2-(hydroxymethyl)-1-methyl-1H-benzo[d]imidazol-5-yl)butan-1-one

생성물 1

HCID 12806656HCID 12806656, 화합물

실험 절차

In a manner analogous to that described in Example 12, 2.7 g of 5-butyryl-6-chloro-1-methyl-benzimidazole-2-methanol are oxidised with 2.5 g of potassium permanganate to give 5-butyryl-6-chloro-1-methyl-benzimidazole-2-carboxylic acid with a melting point of 90° (decomposition).

출처 및 근거

ORD 기록: ord-a2d4daf8498d4d0db4539deefd317847
출처 데이터셋: uspto-grants-1979_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04141982

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