Methyl iodide → HCID 178439609, 화합물

HRID 1399403노트

반응식

HRID 1399403 반응식
[CH2:1]([C:4]1[N:5]=[N:6][N:7]([CH2:9][Si:10]([CH3:13])([CH3:12])[CH3:11])[CH:8]=1)[CH2:2][CH3:3].[I:14][CH3:15]>C(#N)C>[I-:14].[CH3:15][N+:5]1[C:4]([CH2:1][CH2:2][CH3:3])=[CH:8][N:7]([CH2:9][Si:10]([CH3:13])([CH3:12])[CH3:11])[N:6]=1

참가 물질

4

반응물 2

HCID 6328Methyl iodideHCID 131732124HCID 131732124, 화합물

생성물 1

HCID 178439609HCID 178439609, 화합물

시약·촉매·용매 1

HCID 6342Acetonitrile용매

실험 절차

4-propyl-1-((trimethylsilyl)methyl)-1H-1,2,3-triazole and excess iodomethane were added to a vial and heated for about 19 and 5 mL ACN was added. The reaction was heated for another 2 hours. The precipitate was filtered, rinsed with ether and dried in vacuo overnight. The following 3-methyl-4-propyl-1-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium iodide structure was confirmed:

후처리

  1. additionwas added
  2. temperatureThe reaction was heated for another 2 hours
  3. filtrationThe precipitate was filtered
  4. washrinsed with ether
  5. customdried in vacuo overnight

출처 및 근거

ORD 기록
ord-cc5166db45ee4999b0aeb2f941762d4d
출처 데이터셋
uspto-grants-2014_12
특허 번호
US08906135B1

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