Trimethylsilyl cyanide → alpha-(4-Methoxyphenyl)-alpha-(4-methylthioanilino)acetonitrile

HRID 1415751노트

반응식

HRID 1415751 반응식
[CH3:1][O:2][C:3]1[CH:18]=[CH:17][C:6]([CH:7]=[N:8][C:9]2[CH:14]=[CH:13][C:12]([S:15][CH3:16])=[CH:11][CH:10]=2)=[CH:5][CH:4]=1.C[Si]([C:23]#[N:24])(C)C>>[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]([CH:7]([NH:8][C:9]2[CH:14]=[CH:13][C:12]([S:15][CH3:16])=[CH:11][CH:10]=2)[C:23]#[N:24])=[CH:17][CH:18]=1

참가 물질

3

반응물 2

HCID 82115Trimethylsilyl cyanideHCID 21862760N-(4-Methoxybenzylidene)-4-methylthioaniline

생성물 1

HCID 21862854alpha-(4-Methoxyphenyl)-alpha-(4-methylthioanilino)acetonitrile

실험 절차

Following a procedure similar to that described in Example 1(ii), but using N-(4-methoxybenzylidene)-4-methylthioaniline [prepared as described in step (i) above] and trimethylsilyl cyanide as starting materials, the title compound was obtained as a pale brown powder (yield 92%).

출처 및 근거

ORD 기록
ord-fa33ea44b77a4391a936bae6e149642b
출처 데이터셋
uspto-grants-1999_06
특허 번호
US05908858

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