Trimethylsilyl cyanide → alpha-(4-Methylthioanilino)-alpha-(4-sulfamoylphenyl)acetonitrile

반응식

[CH3:1][S:2][C:3]1[CH:20]=[CH:19][C:6]([N:7]=[CH:8][C:9]2[CH:14]=[CH:13][C:12]([S:15](=[O:18])(=[O:17])[NH2:16])=[CH:11][CH:10]=2)=[CH:5][CH:4]=1.C[Si]([C:25]#[N:26])(C)C>>[CH3:1][S:2][C:3]1[CH:4]=[CH:5][C:6]([NH:7][CH:8]([C:9]2[CH:14]=[CH:13][C:12]([S:15](=[O:17])(=[O:18])[NH2:16])=[CH:11][CH:10]=2)[C:25]#[N:26])=[CH:19][CH:20]=1

참가 물질

반응물 2

HCID 82115Trimethylsilyl cyanide

HCID 218628824-Methylthio-N-(4-sulfamoylbenzylidene)aniline

생성물 1

HCID 21862767alpha-(4-Methylthioanilino)-alpha-(4-sulfamoylphenyl)acetonitrile

실험 절차

Following a procedure similar to that described in Example 1(ii), but using 4-methylthio-N-(4-sulfamoylbenzylidene)aniline [prepared as described in step (i) above] and trimethylsilyl cyanide as starting materials, the title compound was obtained as a yellow powder (yield 100%).

출처 및 근거

ORD 기록: ord-f7e5326770e74c7994b0f1d909f33789
출처 데이터셋: uspto-grants-1999_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05908858

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