Pyridine → N'-ethylidene-N-(4-methoxyphenyl)benzohydrazide

HRID 1417415노트

반응식

HRID 1417415 반응식
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([NH:9][N:10]=[CH:11][CH3:12])=[CH:5][CH:4]=1.[C:13](Cl)(=[O:20])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.N1C=CC=CC=1>C(OCC)C>[C:13]([N:9]([C:6]1[CH:7]=[CH:8][C:3]([O:2][CH3:1])=[CH:4][CH:5]=1)[N:10]=[CH:11][CH3:12])(=[O:20])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

참가 물질

5

반응물 3

HCID 1049PyridineHCID 7412Benzoyl chlorideHCID 67504694Acetaldehyde 4-methoxyphenylhydrazone

생성물 1

HCID 53858447N'-ethylidene-N-(4-methoxyphenyl)benzohydrazide

시약·촉매·용매 1

HCID 3283Diethyl Ether용매2회

실험 절차

Combine N-(4-methoxyphenyl)-N'-ethylidene hydrazine (6.0 g, 43 mmol), benzoyl chloride (5.2 mL. 44 mmol), pyridine (3.7 mL, 46 mmol), and diethyl ether (25 mL). After 24 hours, add diethyl ether (100 mL), remove the solid by filtration and dry in vacuo to give N-benzoyl-N-(4-methoxyphenyl)-N'-ethylidene hydrazine as a solid.

후처리

  1. customremove the solid
  2. filtrationby filtration
  3. customdry in vacuo

출처 및 근거

ORD 기록
ord-84cb141d59db4b15901734992a6ecfab
출처 데이터셋
uspto-grants-1999_03
특허 번호
US05877202

반응 노트

불러오는 중…