Hydrochloric Acid → HCID 178429772, 화합물
반응식
[CH3:1][C:2]1([C:8]2[CH:13]=[CH:12][C:11]([OH:14])=[CH:10][CH:9]=2)[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1.Cl.[H][H]>CO.[Rh]>[CH3:1][C:2]1([C@@H:8]2[CH2:9][CH2:10][C@H:11]([OH:14])[CH2:12][CH2:13]2)[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1참가 물질
6
실험 절차
56.1 g (0.29 mol) of 4-(1-methylcyclohexyl)phenol (from 1-methylcyclohexene and phenol in accordance with Chem. Ber. 57 (1924) 857) in 200 ml of methanol to which 1 ml of concentrated hydrochloric acid had been added were hydrogenated at 50° C. with 150 bar of hydrogen in the presence of 5 g of rhodium (5% on charcoal). After removal of the catalyst by filtration with suction, and concentration, 56.1 g (98.5% of theory) remained of an almost pure cis alcohol as a colorless solid.
후처리
- customAfter removal of the catalyst
- filtrationby filtration
- concentrationwith suction, and concentration, 56.1 g (98.5% of theory)
출처 및 근거
- ORD 기록
- ord-41926dadd8f34fad923e195389379f30
- 출처 데이터셋
- uspto-grants-1999_03
- 특허 번호
- US05889012
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