1-Methylimidazole → 1-Methyl-3-(4-vinylbenzyl)imidazolium chloride
반응식
[CH3:1][N:2]1[CH:6]=[CH:5][N:4]=[CH:3]1.[Cl:7][CH2:8][C:9]1[CH:16]=[CH:15][C:12]([CH:13]=[CH2:14])=[CH:11][CH:10]=1>ClC(Cl)(Cl)C>[Cl-:7].[CH3:1][N+:2]1[CH:6]=[CH:5][N:4]([CH2:8][C:9]2[CH:16]=[CH:15][C:12]([CH:13]=[CH2:14])=[CH:11][CH:10]=2)[CH:3]=1참가 물질
4
실험 절차
To a solution of 37.0 g (0.45 mol) of 1-methylimidazol in 200 ml of 1,1,1-trichloroethane was added dropwise a solution of 68.7 g (0.45 mol) of p-chloromethylstyrene in 100 ml of 1,1,1-trichloroethane at room temperature while stirring. After the addition, the mixture was stirred at 65° C. for 10 hours. The resulting product was separated from the reaction mixture, washed with 100 ml of 1,1,1--trichloroethane twice, and dried at 65° C. at 0.1 mmHg for two hours to give 1-methyl-3-(4-vinylbenzyl)imidazolium chloride (MVBI.Cl) as a pale yellow solid. Yield was 52.8 g (50%).