홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /반응

Methyl iodide → HCID 68695542, 화합물

HRID 1437382
노트
인쇄 미리보기

반응식

HRID 1437382 반응식
[CH3:1][O:2][C:3]([C@@H:5]1[CH2:10][CH2:9][C@@H:8]([NH:11][C:12]([O:14][C:15]([CH3:18])([CH3:17])[CH3:16])=[O:13])[C@H:7]([OH:19])[CH2:6]1)=[O:4].[CH3:20]I>ClCCl.[Ag-]=O>[CH3:1][O:2][C:3]([C@@H:5]1[CH2:10][CH2:9][C@@H:8]([NH:11][C:12]([O:14][C:15]([CH3:16])([CH3:18])[CH3:17])=[O:13])[C@H:7]([O:19][CH3:20])[CH2:6]1)=[O:4]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

5

반응물 2

HCID 6328Methyl iodideHCID 68703426HCID 68703426, 화합물

생성물 1

HCID 68695542HCID 68695542, 화합물

시약·촉매·용매 2

HCID 178418778HCID 178418778, 화합물촉매HCID 6344Dichloromethane용매

실험 절차

A mixture of alcohol (d) (6.5 g, 24 mmol), silver(I) oxide (16.5 g, 72 mmol), methyl iodide (4.5 ml) and 3 A molecular sieves (10 g) in dichloromethane (100 ml) was stirred at room temperature for 18 hours. The mixture was filtered and evaporated. The residue was chromatographed on silica eluting with 1:2 ethyl acetate:petrol affording an oil (5.47 g, 80%).

후처리

  1. filtrationThe mixture was filtered
  2. customevaporated
  3. customThe residue was chromatographed on silica eluting with 1:2 ethyl acetate

출처 및 근거

ORD 기록
ord-0e02d90130ec443fa19c9b60d4cb4888
출처 데이터셋
uspto-grants-2009_11
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US07622481B2

반응 노트

불러오는 중…

이 페이지에서참가 물질실험 절차후처리출처 및 근거반응 노트