Benzoyl Peroxide → alpha-Bromo-2-chloro-m-tolyl 2-thienyl ketone
반응식
[S:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]([C:8]1[C:9]([Cl:15])=[C:10]([CH3:14])[CH:11]=[CH:12][CH:13]=1)=[O:7].[Br:16]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[S:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]([C:8]1[C:9]([Cl:15])=[C:10]([CH2:14][Br:16])[CH:11]=[CH:12][CH:13]=1)=[O:7]참가 물질
5
실험 절차
A mixture of 11.8 parts of 2-chloro-m-tolyl 2-thienyl ketone, 8.9 parts of N-bromosuccinimide, 100 parts of carbon tetrachloride and 0.25 parts of benzoyl peroxide is stirred and refluxed for 2 hours. The precipitated succinimide if filtered off and washed on the filter which carbon tetrachloride. The filtrate is dried and evaporated, yielding α-bromo-2-chloro-m-tolyl 2-thienyl ketone as a residue.
후처리
- temperaturerefluxed for 2 hours
- filtrationThe precipitated succinimide if filtered off
- washwashed on the
- filtrationfilter which carbon tetrachloride
- customThe filtrate is dried
- customevaporated
출처 및 근거
- ORD 기록
- ord-bc540702a8944d9ab85d675a44374592
- 출처 데이터셋
- uspto-grants-1977_11
- 특허 번호
- US04060528
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