Iodonium, diphenyl-, bromide (1:1) → Phenyl benzoate

HRID 1447203

반응식

HRID 1447203 반응식
[Br-].[C:2]1([I+:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:15]([O-:23])(=[O:22])[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[Na+]>>[C:15]([O:23][C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1)(=[O:22])[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[C:2]1([I:8])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

참가 물질

4

반응물 2

HCID 73871Iodonium, diphenyl-, bromide (1:1)HCID 517055Sodium Benzoate

생성물 2

HCID 7169Phenyl benzoateHCID 11575Iodobenzene

실험 절차

Diphenyliodonium bromide has been reacted with sodium benzoate to form phenyl benzoate and phenyl iodide, and the reaction has been found to be faster in strong bases. F. M. Beringer, et al., 75 J. Amer. Chem. Soc. 2708 (1963).

출처 및 근거

ORD 기록
ord-d405144759c2449792cd37448bd90a8f
출처 데이터셋
uspto-grants-1982_02
특허 번호
US04316045

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