Iodonium, diphenyl-, bromide (1:1) → Phenyl benzoate

HRID 1447206

반응식

HRID 1447206 반응식
[Br-].[C:2]1([I+:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:15]([O-:23])(=[O:22])[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[Na+]>>[C:15]([O:23][C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1)(=[O:22])[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[C:2]1([I:8])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

참가 물질

4

반응물 2

HCID 73871Iodonium, diphenyl-, bromide (1:1)HCID 517055Sodium Benzoate

생성물 2

HCID 7169Phenyl benzoateHCID 11575Iodobenzene

실험 절차

Diphenyliodonium bromide has been reacted with sodium benzoate to form phenyl benzoate and phenyl iodide, and the reaction has been found to be faster in strong bases. F. M. Beringer, et al., 75 J. Amer. Chem. Soc. 2708 (1963).

출처 및 근거

ORD 기록
ord-8cce7a82156f4b91b7b2eaa733fc1ca6
출처 데이터셋
uspto-grants-1982_02
특허 번호
US04316046

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