Phenylmercuric Acetate → Phenyl acetate

HRID 1447207

반응식

HRID 1447207 반응식
CC(O[Hg]C1C=CC=CC=1)=O.[C:12]([O:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)(=[O:14])[CH3:13].C(OI=O)(=O)C>C(O)(=O)C>[C:12]([O:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)(=[O:14])[CH3:13]

참가 물질

4

반응물 2

HCID 16682730Phenylmercuric AcetateHCID 86738254Phenyl iodoso diacetate

생성물 1

HCID 31229Phenyl acetate

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

The procedure of Example 3 is repeated except that only 10 ml. of acetic acid is charged to the reaction vessel, thereby increasing the concentration of the phenyl mercuric acetate and phenyl iodoso diacetate reactants in the liquid. At the end of the 0.25 hour of reaction at 120° C., phenyl acetate yield is found to be increased to 68%, at a phenyl mercuric acetate conversion of about 72% and a phenyl acetate selectivity of about 94%.

후처리

  1. customAt the end of the 0.25 hour of reaction at 120° C.

출처 및 근거

ORD 기록
ord-a28dddae7f5f4de8b751370c240c3100
출처 데이터셋
uspto-grants-1982_02
특허 번호
US04316046

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