2-Ethylhexanol → 2-ethylhexyl N-methacryloylcarbamate

HRID 1452124

반응식

HRID 1452124 반응식
[C:1]([NH:6][C:7](=O)[O:8]CC)(=[O:5])[C:2]([CH3:4])=[CH2:3].[CH2:12]([CH:14]([CH2:17][CH2:18][CH2:19][CH3:20])[CH2:15][OH:16])[CH3:13]>C1(C=CC(O)=CC=1)O>[C:1]([NH:6][C:7](=[O:8])[O:16][CH2:15][CH:14]([CH2:12][CH3:13])[CH2:17][CH2:18][CH2:19][CH3:20])(=[O:5])[C:2]([CH3:4])=[CH2:3]

참가 물질

4

반응물 2

HCID 77202-EthylhexanolHCID 13628540Ethyl (2-methylacryloyl)carbamate

생성물 1

HCID 199736832-ethylhexyl N-methacryloylcarbamate수율 72.2%

시약·촉매·용매 1

HCID 785Hydroquinone촉매

반응 조건

온도
120 °C

실험 절차

A reaction vessel was charged with 15.7 g of ethyl N-methacryloylcarbamate and 52 g of 2-ethylhexyl alcohol, to which 0.1 g of hydroquinone was added and heated at 120° C. for one hour. The resulting mixture was condensed under reduced pressure and isolated by column chromatography to obtain 17.4 g of 2-ethylhexyl N-methacryloylcarbamate having a viscosity of 800 cp.

후처리

  1. additionwas added
  2. customcondensed under reduced pressure
  3. customisolated by column chromatography

출처 및 근거

ORD 기록
ord-db2484a96fec493cb3de5b738a92ebcb
출처 데이터셋
uspto-grants-1997_02
특허 번호
US05606096

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