Methyldichlorosilane → Silane, 1,1'-(1,2-ethanediyl)bis(1,1-dichloro-1-methyl-

HRID 1460822

반응식

HRID 1460822 반응식
C[CH:2]=[CH:3][SiH:4]([Cl:6])[Cl:5].[CH2:7](C(O)CCCCC)C.[CH3:16][SiH:17]([Cl:19])[Cl:18]>[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[CH3:7][Si:4]([Cl:6])([Cl:5])[CH2:3][CH2:2][Si:17]([CH3:16])([Cl:19])[Cl:18]

참가 물질

5

반응물 3

HCID 6376MethyldichlorosilaneHCID 115273-OctanolHCID 123837375Dichloro-methylvinylsilane

생성물 1

HCID 76881Silane, 1,1'-(1,2-ethanediyl)bis(1,1-dichloro-1-methyl-수율 97%

시약·촉매·용매 1

HCID 61859Chloroplatinic acid촉매

실험 절차

A reactor was charged with 42.3 grams (0.30 mol) of methylvinyldichlorosilane and 0.1 ml of a 2.ethylhexyl alcohol solution containing 2% chloroplatinic acid. To the reactor was added dropwise 34.5 grams (0.30 mol) of methyldichlorosilane. After the completion of addition, stirring was continued for a further one hour. After cooling, the reaction solution was distilled, obtaining 74.5 grams (yield 97%) of 1,2-bis(methyldichlorosilyl)ethane having a boiling point of 109°-110° C./30 mmHg.

후처리

  1. additionAfter the completion of addition
  2. temperatureAfter cooling
  3. distillationthe reaction solution was distilled

출처 및 근거

ORD 기록
ord-f0b18a7921af4e3cadccd2d2f65a182f
출처 데이터셋
uspto-grants-1991_12
특허 번호
US05072012

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