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클로로백금산

Chloroplatinic acid

HCID 61859
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
16941-12-1
표준 SMILES
[Cl][Pt-2]([Cl])([Cl])([Cl])([Cl])[Cl].[H+].[H+]
InChIKey
GBFHNZZOZWQQPA-UHFFFAOYSA-J
분자식
Cl6Pt.2H
평균 분자량
409.8 g/mol

개요

Chloroplatinic acid, is a reddish-brown solid. It is soluble in water and will yield a mildly acidic solution. It may cause illness from inhalation of the dust and it is irritating to skin and eyes. When heated to high temperatures it may decompose to toxic chloride fumes. It may burn, but may be difficult to ignite. It is used for manufacturing indelible ink and in electroplating processes.

이름 및 식별자

우선 이름
Chloroplatinic acid
IUPAC
hexachloroplatinum(2-);hydron
현지명
클로로백금산
영어명
Chloroplantinic acid
분자식
Cl6H2Pt
분자량
409.81

이름 및 동의어

Hexachloroplatinic acidSpeier's catalystDihydrogen hexachloroplatinateHYDROGEN HEXACHLOROPLATINATE(IV)Chloroplatinic(IV) acidPlatinum chloride (H2PtCl6)Hydrogen hexachloroplatinate(4+)Dihydrogen hexachloroplatinate(2-)Platinate(2-), hexachloro-, dihydrogenQ65224GJ7FRefChem:863765DTXCID90809564
이름 더 보기
클로로백금산CPAChloroplatinic acid hexahydratePLATINUM CHLORIDEDihydrogen hexachloroplatinate(IV) solutionHEXACHLOROPLATINIC ACID HYDRATEHydrogen hexachloroplatinate(IV) solutionPL 50Tnsc4958
Hydrogen platinum chloride (H2PtCl6)241-010-716941-12-1Acid platinic chlorideChloroplatinic acidDTXSID30858819Hexachloroplatinic(IV) acidNa2PtCl6

데이터베이스 식별자

CAS
16941-12-1

물성

구조 계산 물성보충 중

극성 표면적
0 Ų
수소 결합 공여자 수
2
수소 결합 수용자 수
1
회전 가능 결합 수
0
무거운 원자 수
7
형식 전하
0
복잡도
62.7

실험 및 물리화학적 성질

Chemical Classes · 2건

Metals -> Metals, Inorganic Compounds

Corrosives

Density2.431 @25 °C
Melting Point60 °C
Physical Description · 3건

Chloroplatinic acid, is a reddish-brown solid. It is soluble in water and will yield a mildly acidic solution. It may cause illness from inhalation of the dust and it is irritating to skin and eyes. When heated to high temperatures it may decompose to toxic chloride fumes. It may burn, but may be difficult to ignite. It is used for manufacturing indelible ink and in electroplating processes.

Dry Powder; Liquid; Liquid

Reddish-brown solid; Soluble in water; [CAMEO] Brownish or yellow crystals; Deliquescent; Odorless or mild odor of hydrogen chloride; [GFS Chemicals MSDS] Exists as hexahydrate; [Merck Index]

물리화학적 성질

녹는점
60 °C · 60 °C(lit.)
밀도
2.43 g/mL · 2.43 g/mL at 25 °C(lit.)
증기압
0 Pa · 0Pa at 20℃
굴절률
20 · n20/D 1.347
저장 조건
2 · 2-8°C
용해도
2 O: · H2O: 0.5 M at 20 °C, 투명, 주황색

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

P233, P260, P261, P264, P270, P271, P272, P280, P284, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P330, P333+P317, P342+P316, P362+P364, P363, P403, P405, and P501 (click each P-code to see the statement)

Danger

H290 (65.8%): May be corrosive to metals [Warning Corrosive to Metals]

P233, P234, P260, P261, P264, P264+P265, P270, P271, P272, P273, P280, P284, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P333+P317, P342+P316, P362+P364, P363, P390, P391, P403, P405, P406, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 6건

Chemical: Platinate(2-), hexachloro-, dihydrogen, (OC-6-11)-

Hazard Traits - Respiratory Toxicity

Hazard Traits - Respiratory Toxicity

Platinate(2-), hexachloro-, hydrogen (1:2), (OC-6-11)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Platinate(2-), hexachloro-, hydrogen (1:2), (OC-6-11)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 05-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/21738

Hexachloroplatinic acid: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Platinate(2-), hexachloro-, dihydrogen, (OC-6-11)-: Environment tier I assessment
DOT LabelCorrosive
Fire Hazards · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

화학 및 산업

용도 및 제조

Uses · 2건

Used in plating, photography, mirrors, indelible inks, luster on glass, and acetic acid manufacturing; Also used for platinizing pumice stone, catalyzing sulfur trioxide production, relief etching of zinc (artistic and commercial applications), and fixing microscope preparations; [Merck Index] Used in electroplating; [CAMEO]

Electroplating [Category: Plate]

U.S. Production2023: 250,000 - <550,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesIntermediate
General Manufacturing Information · 2건

Electrical Equipment, Appliance, and Component Manufacturing

Platinate(2-), hexachloro-, hydrogen (1:2), (OC-6-11)-: ACTIVE

응용 분야 · 2건

용도Chloroplantinic acid (H2PtCl6) is one of the most commercially important compounds of platinum. Its many uses include etching on zinc, making indelible ink, plating, and coloring in fine porcelains and use in photography, in mirrors, and as a catalyst.

일반 설명Chloroplatinic acid, is a reddish-brown solid. Chloroplatinic acid is soluble in water and will yield a mildly acidic solution. Chloroplatinic acid may cause illness from inhalation of the dust and Chloroplatinic acid is irritating to skin and eyes. When heated to high temperatures Chloroplatinic acid may decompose to toxic chloride fumes. Chloroplatinic acid may burn, but may be difficult to ignite. Chloroplatinic acid is used for manufacturing indelible ink and in electroplating processes.

상·하류 제품 정보

상류 원료

백금분PT-C

관련 반응

136건
반응 기록 만들기
HRID 2355 반응식
HRID 2355촉매로uspto-grants-1998_03
HRID 6444 반응식
HRID 6444촉매로uspto-grants-1993_09
HRID 6447 반응식
HRID 6447촉매로uspto-grants-1993_09
HRID 6449 반응식
HRID 6449촉매로uspto-grants-1993_09
HRID 6451 반응식
HRID 6451촉매로uspto-grants-1993_09
HRID 37599 반응식
HRID 37599촉매로uspto-grants-1995_05
HRID 37600 반응식
HRID 37600촉매로uspto-grants-1995_05
HRID 37601 반응식
HRID 37601촉매로uspto-grants-1995_05
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화합물 노트

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더보기
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PubChem CID
61859
EC Number
241-010-7
물리적 상태
가루와 덩어리
색상
오렌지 레드
수용성
녹는
Merck
14 · 14,7526
안정성
빛, 공기 또는 습기에 노출되면 분해될 수 있습니다.
화장품 원료 기능
계면활성제 - 세정
InChI
InChI=1S/6ClH.Pt/h6*1H;/q;;;;;;+4/p-4
InChIKey
GBFHNZZOZWQQPA-UHFFFAOYSA-J
SMILES
[Pt](Cl)(Cl)(Cl)Cl.Cl.Cl
EPA
Platinate(2-), hexachloro-, hydrogen (1:2), (OC-6-11)- (16941-12-1)

화학적 성질

Orange/Red Crystals

Health Hazards · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.

Hazards Summary · 1건

May cause asthma or dermatitis; [Merck Index] A skin and eye irritant; [CAMEO] Hydrate is CAS# 26023-84-7; A skin and eye irritant; Harmful by ingestion and inhalation; Chronic exposure may cause sensitivity; [GFS Chemicals MSDS] Solution: Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause respiratory sensitization; Toxic by ingestion; [Sigma-Aldrich MSDS] See Platinic chloride hexahydrate.

DOT ID and Guide2507 154
Reactive GroupAcids, Weak
Reactivity Profile · 1건

Oxidizing acids are generally soluble in water with the release of hydrogen ions. The resulting solutions have pH's of less than 7.0. Materials in this group react with chemical bases (for example: amines and inorganic hydroxides) to form salts. These neutralization reactions occur as the base accepts hydrogen ions that the acid donates. Neutralizations can generate dangerously large amounts of heat in small spaces. The dissolution of acids in water or the dilution of their concentrated solutions with water may generate significant heat. The addition of water acids often generates sufficient heat in the small region of mixing to boil some of the water explosively. The resulting "bumping" spatters acid widely. These materials have significant ability as oxidizing agents. but that ability varies (for example, from high for nitric acid to low for sulfuric acid and most sulfonic acids). They can react with active metals, including iron and aluminum, and also many less active metals, to dissolve the metal and liberate hydrogen and/or toxic gases. Like other acids, materials in this group can initiate polymerization in certain classes of organic compounds. Their reactions with cyanide salts and compounds release gaseous hydrogen cyanide. Flammable and/or toxic gases are also often generated by their reactions with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and weak or strong reducing agents. Additional gas-generating reactions occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), and even carbonates: the carbon dioxide gas from the last is nontoxic but the heat and spattering from the reaction can be troublesome. Acids often catalyze (increase the rate) of chemical reactions.

DOT Hazard Classification · 4건

Chloroplatinic acid, solid

UN2507

Class 8 Corrosive material (49 eCFR § 173.136)

PG III: the degree of danger presented by the material is minor

Air and Water ReactionsSoluble in water.
Hazard Classes and Categories · 6건

Met. Corr. 1 (65.8%)

Acute toxicity - category 3

Respiratory sensitization - Category 1

Serious eye damage/eye irritation - Category 1

Corrosives, Reactive agents - 1st degree

Acute Tox. 3 *

안전 및 보호

Fire FightingExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Isolation and Evacuation · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Immediate precautionary measure

Threshold Limit Values (TLV)0.002 [mg/m3], as Pt
Permissible Exposure Limit (PEL)0.002 [mg/m3], as Pt
Protective Action Criteria (PAC) · 3건

0.013 [mg/m3]

3.2 [mg/m3]

19 [mg/m3]

Personal Protective Equipment (PPE)Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Emergency Response Planning GuidelinesSmall Fire
Immediately Dangerous to Life or Health (IDLH)4 mg Pt/m3 (NIOSH, 2024)

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

안전 데이터

wgk
1
tsca
TSCA listed
rtecs
TP1510000
ridadr
UN 2507
HS 번호
28439000
risk_code
25-34-42/43-36/38-36/37/38-22
hazard_code
T,C,Xi
safety_code
26-27-36/37/39-45-22-23
포장분류
III
위험 등급
8
기존화학 물질
KE-18416
F 고인화성물질
3-8-10
Hazard Classifications
Acute Tox. 3 OralAquatic Chronic 2Eye Dam. 1Met. Corr. 1Resp. Sens. 1Skin Corr. 1BSkin Sens. 1STOT RE 2
스토리지 클래스
6.1B - Non-combustible acute toxic Cat. 1 and 2very toxic hazardous materials
염화플레티넘산 암모늄
염화 암모늄
질산

하류 제품

hydrofining catalysts for raffinate oil

추가 설명

정의chloroplatinic acid: A reddish crystallinecompound, H2PtCl6, made bydissolving platinum in aqua regia.