1,3-Dinitrobenzene → 3-Nitroanisole

HRID 1461899

반응식

HRID 1461899 반응식
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+]([O-])=O)[CH:5]=1)([O-:3])=[O:2].[CH3:13][O-:14].[Na+]>CN(P(N(C)C)(N(C)C)=O)C>[N+:1]([C:4]1[CH:5]=[C:6]([O:14][CH3:13])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2]

참가 물질

4

반응물 2

HCID 74521,3-DinitrobenzeneHCID 10942334Sodium Methoxide

생성물 1

HCID 111403-Nitroanisole

시약·촉매·용매 1

HCID 12679Hexamethylphosphoramide용매

실험 절차

m-Nitroanisole was prepared by reacting m-dinitrobenzene with sodium methoxide at 25° C. for 16 hours in hexamethylphosphotriamide solvent (N. Kornblum et al., J. Org. Chem., 41, 1560 (1976)).

후처리

  1. customat 25° C.
  2. customfor 16 hours

출처 및 근거

ORD 기록
ord-ed9cb278273043408beb7f1e17df48d2
출처 데이터셋
uspto-grants-1991_12
특허 번호
US05077436

연결된 노트

불러오는 중…